Project  Stories

Ion exchange Resins for Purifying Electronic Materials
Removing residual metallic impurities
for the semiconductor manufacturing industry,
down to the parts per trillion level.
Project start

It is no exaggeration to say that modern life, society, and industry would not be possible without semiconductors. Ion exchange resins are a crucial technology for purifying the electronic materials required to create semiconductors, and it's a technology in which Organo has built up extensive expertise over many years.

The main purpose of ion exchange resin was originally to remove impurities from water in order to produce pure water and ultrapure water. However, we recognized its potential for removing impurities from electronic materials, including non-aqueous organic solvents. It’s an insight we gained more than 20 years ago. Any impurities left in electronic materials would not only cause critical issues such as malfunctions and system freezes, but would make it impossible to manufacture parts in the first place.

Year after year, semiconductor products become smaller, and the level of purity required of electronic materials is increasing proportionally. In the past, the allowable level of impurities was a tiny amount, equivalent to a few milligrams in an Olympic-sized swimming pool. Today, the required purity is so extreme that even the same amount in a vast lake would be too much. Achieving this has required superhuman feats of research, development, and commercialization. We spoke with four key people involved in these processes to reveal the whole story of the challenges they faced.

*Parts per trillion: A unit of measurement used to indicate purity. Technology has advanced to the point where the range of parts per quadrillion (ppq) is about to be reached.

Project member
  • A photo of Miwa Ito

    Miwa Ito

    Ito was assigned to the project from the very start of developing ion exchange resins for purifying electronic materials, roughly 20 years ago. She was involved in everything from development to mass production, customer proposals, and technical support. She is now General Manager of the Functional Materials Dept., Performance Products Business Division.

  • A photo of Akira Nakamura

    Akira Nakamura

    Nakamura was responsible for development during the project. He performed a range of duties, including proposing technology to customers, conducting basic lab evaluations, and verifying implementation. He now works within the High-Purity Technology Group, Organo R & D Center.

  • A photo of Michiyuki Ishihara

    Michiyuki Ishihara

    Ishihara was assigned to the ion exchange resins for purifying electronic materials project from the very beginning, and was responsible for sales. He oversaw operations in the Japanese and global markets. He is now General Manager of the Separation and Refinement Sales Dept., Performance Products Business Division.

  • A photo of Toshiaki Nihei

    Toshiaki Nihei

    Nihei was responsible for sales during the project. He was responsible for submitting sales proposals to customers in Japan, Taiwan, China, and South Korea, and was also responsible for establishing and promoting the sales organization. He now works within the Separation and Refinement Sales Dept., Performance Products Business Division.

Focus 1

Providing support as the last bastion
in overcoming the "cleaning barrier"

The technical context of using ultrapure water cleaning technology

During the early 2000s, Organo had reached a turning point in technology, built on a foundation of working with ultrapure water. The R&D Division continued to seek out needs for solvents other than ultrapure water, as well as synergies with ion exchange resin for removing impurities. Miwa Ito, who was assigned to the project as the main member from development, reflects back on that time.

"In the R&D Division, we were working on technology to purify organic solvents. This was an initiative conducted in collaboration with the business divisions, and it had the potential to overcome the "cleaning barrier" that semiconductor and electronic material manufacturers were facing. We realized that we could address the concerns of many of our customers if only we could apply and develop cleaning technology based on our work with ultrapure water. This was our source of synergy, and the project expanded rapidly into a company-wide initiative in which engineering, sales, and management all worked together."
This marked the full-scale launch of the project for ion-exchange resins used in the purification of electronic materials.

However, Organo lacked knowledge of solvent electronic materials at that time. Ito and the other engineers began visiting customers together with salespeople from the business divisions.
"We began developing an understanding as we spoke with more and more customers, and then we started to identify some of the issues we needed to address. What materials need to be removed? What level would be acceptable? How can we use ion exchange resins? As the days went on, we started developing more accurate hypotheses, and our technologies ultimately became products."

The market context requiring an extra level of purity

A wide variety of electronic materials are used in the processes for manufacturing semiconductors, and the issue of trace impurities was of great concern to semiconductor and electronic material manufacturers. Michiyuki Ishihara, who was in sales at the time and remembers the conditions they were facing, explains.

"Although ultrapure water required for semiconductor manufacturing had achieved purity close to the theoretical limit, the poor purity of electronic materials was causing wafer contamination. You can't make semiconductors without clean water and electronic materials. We told electronic material manufacturers about the concerns we were hearing from semiconductor manufacturers, and ultimately developed a solution over the course of many meetings."

For electronic material manufacturers, poor yields caused by insufficient purity had become a serious bottleneck.
"There were many semiconductor manufacturers concerned about residual impurities in electronic materials, which could prevent them from actually making products," Ishihara continues. "One example is distillation equipment, which uses differences in the boiling points of substances to remove impurities. We were hearing concerns about residual metallic impurities left by the equipment itself, as well as difficulties in removing impurities with boiling points close to that of the target substance. Our customers wanted an extra level of cleanliness to make sure that the last mile of manufacturing goes smoothly. I realized that our ion exchange resin would be crucial in bridging the gap between manufacturers and suppliers."

Back in 2000, the semiconductor manufacturing divisions of Japan's electronics manufacturers were among the world's top semiconductor manufacturers, and they were pushing to develop even more advanced products. Ion exchange resins for purifying electronic materials were exactly the advanced technology that the industry needed at that time.

Further boosting demand and pursuing technology

Demand for ion exchange resins for purifying electronic materials has increased tenfold over the past decade. Business is also expected to increase tenfold over the next decade. According to Toshiaki Nihei, who works in technical sales, this is due to the expanding scope for high purification and increasingly strict requirements.

"Logic semiconductors continue to decrease in size as we approach the 3 nm* and 2 nm generations of products. The level at which impurities must be removed is becoming stricter, while more types of impurities are also needing to be removed. The challenge has now shifted toward domains that are difficult for conventional technologies, and customers are increasingly making use of new ion exchange resins. Meanwhile, demand for semiconductor products themselves is increasing due to expanding use of technologies such as AI and data centers, and the switch to multifunctional smartphones and vehicles. This is also boosting demand for existing ion exchange resins."

Ishihara elaborates: "Semiconductors are becoming increasingly faster, and the scope of the level at which electronic materials are cleaned is expanding. What's considered advanced technology today will be considered standard technology five years from now, and then new technology will be released. In supporting the semiconductor industry, we need to always continue to keep up with the latest advanced technology."

*Nanometer. One nm is equal to one billionth of a meter. Numbers continue to decrease as the ultra-high performance of semiconductors increases.

Focus 2

Developers working to overcome
the unique challenges of each project​

Developing optimal solutions from scratch

The greatest barrier in the way of removing impurities from electronic material is the fact that each material is unique. In other words, the raw materials and what is being purified vary from customer to customer, and a purification process unique to each material must be designed. Making things even more difficult is the fact that a lot of information cannot be disclosed.

Akira Nakamura, who was responsible for development, explains.
"These are core technologies for our customers, and there are many cases where they cannot disclose information on what needs to be purified, even to their technical partners. We need to remove metallic impurities without knowing what the solvent is. However, even if we are able to remove the impurities, it would be meaningless if we ended up damaging that solvent. That's why we have multiple discussions with the customer, develop hypotheses, and then narrow down which ion exchange resin candidates, combinations, and treatment methods we could use. It was very challenging."

Development requires a deep understanding of both ion exchange resins and what to purify, and the ability to infer what will happen when substances are mixed. It also requires leveraging knowledge gained through previous projects.
"There's nothing greater than the joy you get from solving a problem," adds Akira with a big grin.

Repeated trial and error to increase the level of certainty

Optimizing ion exchange resins for each customer involves several steps. The first step is to determine what to purify, what to remove, and what level of purification is required. The next step is to determine what kind of ion exchange resin, or combination of resins, to use. The final step is implementation through a process of lab and scale-up evaluations.

"Based on the information and requirements we obtain through discussion with the customer, we come up with a technical hypothesis and conduct small-scale experiments, at an amount of several tens of milliliters," Nakamura elaborates. "If a substance shows some promise during screening, we start scaling up to several hundreds of milliliters, several liters, and then several tens of liters. Some experiments don't go well, but even those provide us with valuable insight, so none of our experiments or verifications are a waste of time."

Feedback from the customer is also very important for this process of trial and error.
"We provide ion exchange resins based on our hypotheses and then ask our customers to evaluate them. This process is extremely important," explains Nihei. "After providing a product, we make sure to confirm the customer's evaluation. If any new issues were found, we take it back to the development team. We continue to do this until we develop the right product for the job."

Manufacturers and suppliers involved in semiconductor manufacturing are working on novel projects at the forefront of technology. Organo provides support to these customers at the forefront.

Unlimited opportunities to contribute in a wide range of areas

Organo's ion exchange resins are used to clean electronic materials as thoroughly as possible, and they play an important role in the electronics industry. But the contributions made by these products do not stop there. Ishihara has had many opportunities to interact with customers in various fields and sees the technology expanding into other industries.

"There's a technology called chromatographic separation, where you use the differences in adsorption affinity and migration speed between substances to separate components mixed together, and ion exchange resins excel in this area. We've been getting requests from companies in the medical, pharmaceutical, and bio-tech fields, and demand is also growing for companies involved in recycling electronic materials, where purity is a key factor."

Ito expands on Ishihara's comment. "The principle remains the same. What changes are the needs of the time. Ion exchange resins have been used in various industries for a very long time. In the food sector, these were first used for superfine sugar, and then use expanded to functional food products and health food products. In the energy sector, they're used with thermal and atomic power generation, hydrogen, and products like fuel cells. It's truly exciting to see how the use of ion exchange resins changes to meet new needs as times change." Ion exchange resins will continue to provide flexible support during an era of constant change.

Focus 3

Passing down the spirit of Organo
from one generation to the next

Building trust based on Organo's unique strengths

While there are other technologies for removing impurities from electronic materials, Organo made the decision to go with ion exchange resins. Why is that? According to Nihei, it's the "overall capabilities" they provide.

"Our products help to purify substances at a level that other companies cannot match, customized for each request we receive. Doing this requires the ability to communicate and draw out the customer's thoughts and goals. The greatest value we provide is in sales and development always working together to solve our customers' problems, and I take a lot of pride in that. I think that you need a solid technical sales foundation that goes beyond just sales in order to come up with a hypothesis and draw out the customer's reaction to it."

Nakamura feels the same way.
"Our core strengths are the high quality of our ion exchange resins and our wide lineup of products, but just having good products isn't enough to win a customer over," he explains, revealing his inner thoughts as an engineer. "It's crucial for development and sales to work together in order to build a trust relationship with customers, where the customer is happy that they came to us for help. Just like how Nihei is gaining a technical background through experience, I'm learning how to handle sales-related work, so it's like we're helping each other to improve our skills."

It is also important to share information obtained from customers with the rest of the team. Nihei provides an example.
"We really focus on creating ways to collect information from customers and share it within the department and with the development team. Doing this as an organization allows us to submit highly accurate proposals quicker, and this also helps promote the development of new resins."
This continuous process of sharing information is itself becoming one of Organo's strengths.

Passing down technology, know-how, and a mindset of finding work "interesting"

It is thanks to the communication skills, technical skills, proposal skills, and co-creation skills of its employees that Organo is able to provide highly refined products to address customers' challenges. How are these skills developed and passed down? We asked Michiyuki, Toshiaki, Miwa, and Akira about their perspective on work.

Ishihara

Ishihara

"Ever since that time 20 years ago, I've found taking on new challenges to be both rewarding and interesting. Training and education are both crucial, but I think it's important to first develop a mindset of finding your work to be interesting. I can see the same thing in Nihei. He really seems to be fully interested whenever he takes on a new challenge. This is really the most important thing, and I hope it will resonate with our younger employees, too."

Nihei

Nihei

"Organo is closely associated with water, so it's very exciting when you're working on a project unrelated to water. I found this project to be very interesting since we were able to contribute to the semiconductor field, which is driving technological advancements today, and the work also played a key role in developing new businesses for us, which is very rewarding. That's the real pleasure of doing this kind of work, and I'd like to convey that to our younger employees."

Ito

Ito

"Developing a solution while asking the customer directly about the issues they're having is quite a rare opportunity, even within Organo. The sense of accomplishment you feel after solving a problem like this is so great that it really can't be put into words. I'd like our younger employees to develop skills through experience, and to never give up on a challenge even if they hit a wall. Continuing to challenge yourself is how you develop the proper mindset for development."

Nakamura

Nakamura

"Working with a customer's cutting-edge technology is very rewarding and brings me a lot of joy as a developer. There are times when your experiments don't go well, but being the first to see the results is the real joy of working as an engineer. I'd like to do my part in developing the next generation of engineers who will find the entire process interesting and apply what they've learned to future work, regardless of the field and regardless of whether the project is related to water."

In the electronics industry, demand for semiconductors is expected to become increasingly diverse and advanced, beginning with the widespread adoption of generative AI. As for Organo's ion exchange resins, the company will continue to refine its advanced cleaning technology to meet even greater expectations.

Project overview

■ Technology

Ion exchange resins for purifying electronic materials

■ Period

From 2000 to now (development ongoing)

■ Used by

Many semiconductor manufacturers and electronic material suppliers